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  7. 1,1'-(Azodicarbonil)dipiperidina, 97 %, Thermo Scientific Chemicals

1,1'-(Azodicarbonil)dipiperidina, 97 %, Thermo Scientific Chemicals

Catalog Number 11392839
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Cantidad:
5 g
25 g
10465-81-3
C12H20N4O2
252.32
MFCD00010111
OQJBFFCUFALWQL-UHFFFAOYSA-N
1,1'-azodicarbonyl-dipiperidine, 1,1-azodicarbonyl dipiperidine, 1,1'-azodicarbonyl dipiperidine, addp, diazene-1,2-diylbis piperidin-1-ylmethanone, azodicarboxylic acid dipiperidine, ne-n-piperidine-1-carbonylimino piperidine-1-carboxamide, 1,1'-azodicarbonyl dipiperidine addp, piperidyl piperidylcarbonyl diazenyl ketone, e-diazene-1,2-diylbis piperidin-1-ylmethanone
5702657
N-[(piperidine-1-carbonyl)imino]piperidine-1-carboxamide
O=C(N=NC(=O)N1CCCCC1)N1CCCCC1
10465-81-3
C12H20N4O2
252.32
MFCD00010111
OQJBFFCUFALWQL-UHFFFAOYSA-N
1,1'-azodicarbonyl-dipiperidine, 1,1-azodicarbonyl dipiperidine, 1,1'-azodicarbonyl dipiperidine, addp, diazene-1,2-diylbis piperidin-1-ylmethanone, azodicarboxylic acid dipiperidine, ne-n-piperidine-1-carbonylimino piperidine-1-carboxamide, 1,1'-azodicarbonyl dipiperidine addp, piperidyl piperidylcarbonyl diazenyl ketone, e-diazene-1,2-diylbis piperidin-1-ylmethanone
5702657
N-[(piperidine-1-carbonyl)imino]piperidine-1-carboxamide
O=C(N=NC(=O)N1CCCCC1)N1CCCCC1

Descripción

It is used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides. It is widely used reagent for the Mitsunobu reaction. It is reactant for preparation of polyfluoroalkylated tripyrazolylmethane ligands, (-)-Hygromycin A via Mitsunobu glycosylation, optically active α,α-disubstituted amino acids via Mitsunobu reaction, aza-β-lactams through [2+2] cycloaddition reactions, glycosyl disulfides, pyridine ether PPAR agonists, S-glycosyl amino acid, building blocks for combinatorial neoglycopeptide synthesis and is a histamine H3 receptor antagonists. It is a reactant for Mitsunobu inversion reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Aplicaciones
Se utiliza en un estudio de la adición catalizada por cobre de ácidos ariborónicos a derivados de azodicarboxilo que proporcionan hidrazidas sustituidas por arilo. Es un reactivo ampliamente utilizado para la reacción de Mitsunobu. Es reactivo para la preparación de ligandos de trispirazolilmetano polifluoroalquilado; (-)-higromicina A mediante glicosilación de Mitsunobu; aminoácidos α,α-disustituidos ópticamente activos mediante reacción de Mitsunobu; aza-β-lactamas mediante reacciones de cicloadición [2+2]; glicosildisulfuros; agonistas de PPAR del éter de piridina; aminoácido S-glicosil; compuestos básicos para la síntesis combinatoria de neoglucopéptidos. Además, es un antagonista del receptor de la histamina H3. Es un reactivo para las reacciones de inversión de Mitsunobu.

Solubilidad
Ligeramente soluble en agua.

Notas
Almacenar en condiciones secas y frías. Incompatible con los agentes oxidantes.
TRUSTED_SUSTAINABILITY
Nombre del producto químico o material 1,1'-(Azodicarbonyl)dipiperidine
Punto de fusión 133°C to 136°C
Olor Odorless
Cantidad 25 g
Información de solubilidad Slightly soluble in water.
Formula Weight (peso de la fórmula) 252.32
Porcentaje de pureza 97%

RUO – Research Use Only

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